This work aims at maximizing the productivity of emulsion homopolymerization processes. A dynamic model of emulsion polymerization processes is extended by the inclusion of vaporization from the liquid phases in the reactor to the gaseous phase. The multi-component gas-liquid mass transfer phenomenon is described by the Maxwell-Stefan diffusion equations, which are solved by a special algorithm. A novel operation strategy is developed for running a reactor optimally with respect to batch time. This strategy is applied first to an industrial scale reactor, which is run without using evaporative cooling. Then, based on the extended model, controlled vaporization is included by which additional heat is removed from the reaction system. This makes it possible to extend the restrictions imposed by the limited heat removal of the cooling jacket considerably. Simulation results are presented for the homopolymerization of vinyl acetate in an industrial scale reactor operated in semi-batch mode. The results show that a significant amount of heat can be removed by evaporative cooling thus leading to higher productivity. (c) 2006 Elsevier Ltd. All rights reserved.