화학공학소재연구정보센터
Thermochimica Acta, Vol.455, No.1-2, 80-85, 2007
Densification kinetics of MnO-doped UO2-10wt%Gd2O3 compact
The effect of MnO doping on the densification behavior of the UO2-10 wt%Gd2O3 compact has been investigation high-temperature pushrod dilatometer up to 1650 degrees C. Dilatometry results show that small amounts of MnO enhance the sintering of the UO2-10 w%Gd2O3 Compact leading to a very high densification rate at low temperatures of about 1250 degrees C. The sintered density substantially was increased by more than 1% of the theoretical density in only 0.01 wt% of MnO added sample. A small amount of MnO also promotes the grain growth dramatically. The UO2-10 wt%Gd2O3 pellet with 0.1 wt% of MnO shows a 2.5 times larger grain size than the undoped UO2-10 wt%Gd2O3 pellet. These results might be attributed to the enhanced grain boundary mobility, which probably resulted from a large distortion of the surrounding lattice. (C) 2006 Elsevier B.V. All rights reserved.