Novel Ru-2-containing dendritic compounds were prepared from the Cu-I-catalyzed 1,3-dipolar cycloaddition between Ru-2 compounds containing one or two ethynes, Ru-2(D(3,5-Cl2Ph)F)(4-n)(DMBA-4-C2H)(n) with n = 1 and 2, and azidopoly(benzyl ether) dendrons. These new compounds were also characterized with X-ray diffraction and voltammetric techniques.