Ab initio MP2/6-311++G(2d,2p) investigation of the SO2/OH/NO singlet potential energy surface (PES) has been performed with the aim to localize and describe the existing minima and transition states linking them. The systematic studies have revealed seven minima, with the trans-HONO-SO2 complex (1t) being the global minimum. Eight transition states between minima or between minima and the relevant reactant species have been described. Several available izomerization and dissociation routes have been identified and discussed. The most favorable association of HOSO2 and NO was found to be a barrierless process forming nitrososulfonic acids. Isomerizations between trans-, cis-, and gauche- nitrososulfonic acids (2t, 2c, and 2g) are possible with low-energy barriers. The HOSO2 and NO species can also react via another channels involving high-energy transition states to produce the HOSO-NO2 (3) and HNO-SO3 (4) complexes.