화학공학소재연구정보센터
Polymer Engineering and Science, Vol.47, No.5, 593-607, 2007
Predictions of two nonlinear viscoelastic constitutive relations for polymers under multiaxial loadings
Two viscoelastic constitutive relations in differential form are further developed here to include material nonlinearity and distinction between loading and unloading regimes, which is a characteristic of polymers. The effects of hydrostatic pressure and anisotropy in tension and compression on the deformation response of polymers are accounted for through the definition of a pressure-dependent equivalent stress. In the uniaxial stress state, these constitutive relations reduce to the two well-known mechanical analogue representations: "Kelvin-Voigt-type" and "Maxwell-type" rheological models. The predictive capabilities of these constitutive relations are then assessed against a wide range of experimental results, which include both uniaxial and biaxial stress states subjected to quasi-static and cyclic-loading conditions. The predictions of both models are found to be in good agreement with the test data.