A sequential process is used to synthesise CulnS(2) absorber layers for photovoltaic application. In this process CuIn precursor layers sputtered on molybdenum coated float glass are converted to CuInS2 via sulphurisation in an elemental sulphur vapour ambient. A re-evaluation of process parameters has been performed including fine tuning of numerous minor aspects. Using optimised process conditions has led to improved device performance, especially a narrowed distribution at higher module efficiencies is achieved. At the same time the process yield is improved resulting in fewer devices with poor electrical quality. (C) 2006 Elsevier B.V. All rights reserved.