화학공학소재연구정보센터
Chemical Physics Letters, Vol.321, No.3-4, 205-215, 2000
Symmetry principles for the design of radiofrequency pulse sequences in the nuclear magnetic resonance of rotating solids
Some new symmetry theorems are presented which simplify the task of designing multiple-pulse radio-frequency pulse sequences in magic-angle-spinning solid-state NMR. The symmetry theorems apply to sequences denoted RNnv which consists of N repetitions of a pulse sequence element R, alternating in phase between the values +/- pi v/N. Each R element ideally rotates the spins by an angle pi about the rotating frame x-axis. The entire RNnv sequence is timed to span n rotational periods. Applications are presented for homonuclear double-quantum and zero-quantum recoupling, heteronuclear decoupling and heteronuclear recoupling.