Normal coordinate calculations were performed by the density functional method of B3LYP/6-311 + G * * on 205 basic organic and inorganic compounds taken from the 'Tables of Molecular Vibrational Frequencies' (T. Shimanouchi, 1972). The calculated wavenumbers, nu(calc), of 1729 vibrational modes were correlated with the observed wavenumbers, nu(obs), by a single least-squares fitting. The relationship obtained, after omitting the vibrational modes that give deviations of more than 10%, is nu(obs)/nu(calc) 1.0087-0.0000163 (nu(calc)/cm(-1)). The wavenumber-linear scaling method with this relationship predicts vibrational wavenumbers with high accuracy and is applicable to any compounds, except for the compounds for which the effect of dispersion forces is significant.