We present a study of the fundamental photoexcitations in a phenylenevinylene conjugated polymer from the visible to the mid-infrared (IR) using polarized subpicosecond transient absorption (TA) spectroscopy. From 0.5 to roughly 1.3 eV we find that features due to singlet intrachain excitons dominate the photoinduced absorption. Two peaks are apparent in the spectrum: one near 0.5 eV and the other at similar to1.1 eV. In the regime of high excitation densities (> 10(19) cm(-3)), we find evidence of exciton-exciton interactions leading to exciton hopping between different chains or segments of the polymer.