Chemical Physics Letters, Vol.330, No.3-4, 417-422, 2000
Observation of Na(2)2(3)Pi(g)-1(3)Sigma(+)(u) bound-free emissions generated from Na(3p) in a reactive oxidation process
The chemiluminescent reaction products of the (Na, Na-2) + Br halogenation system at concentrations in excess of 10(12) cm(-3) are considered. In a purely reaction driven environment evidence is obtained for the formation of the Na-2 2(3)Pi (g) excited state and bound-free emission associated with the 2(3)Pi (g) - 1(3)Sigma (+)(u) band system.