Chemical Physics Letters, Vol.344, No.1-2, 92-96, 2001
Infrared laser spectrum of the fundamental band of the boron monoxide free radical
The infrared diode laser absorption spectrum of the fundamental band of the boron monoxide (BO) radical in its ground (2)Sigma (+) state has been observed. The source of the radical was the reaction of BCl3 with (OP)-P-3 in the absence of molecular oxygen. 15 lines of (BO)-B-11 and three lines of (BO)-B-10 have been measured. The (BO)-B-10 lines show a small, partially resolved, doublet structure of about 0.01 cm(-1) which is not present in the (BO)-B-11 species. This is attributed to the complex hyperfine pattern expected for the B-10 (I = 3) nucleus. The band origins are 1861.92465(48) and 1915.30554(16) cm(-1), respectively. Combining the diode laser value of B-t = 1.756829(11) cm(-1) with the microwave determination of B-o leads to a value of r(c) = 1.204068(7) Angstrom. for (BO)-B-11.