Vibrational effects on NMR shielding constants and nuclear spin-spin coupling constants have been investigated in a model hydrogen-bonded complex, CNH:NCH. Expectation values of the spin-spin coupling constant (2h)J(N-N), obtained from a two-dimensional EOM/CCSD/(qzp,qz2p) surface, and of the isotropic proton shielding constant sigma (H), obtained from a two-dimensional MP2/(qzp,qz2p), surface, are presented as functions of vibrational state. The expectation values have been computed from anharmonic dimer- and proton-stretching vibrational wavefunctions obtained from a two-dimensional MP2/aug'-cc-pYTZ potential surface. Equilibrium values, ground-state expectation values, and thermally averaged values at 298 K of (2h)J(N-N), and sigma (H) are compared.