Experiments employing mass-selected ion deposition in neon matrices confirm that a spectrum with origin near 440 nm, which we have previously reported. indeed corresponds to the C5N2 mass, as tentatively assigned. The spectrum consistently appears when mass 88 is deposited, but is absent when other CmNn species are selected. We discuss the observed spectra in light of the recently reported theoretical density functional calculations, as well as new calculations which we have carried out. Taking into consideration computed band frequencies, observed isotopic shifts. and spectroscopic selection rules, consistent assignments for all the nine observed vibrational frequencies of the carrier can be proposed. (C) 2002 Elsevier Science B.V. All rights reserved.