Chemical Physics Letters, Vol.351, No.5-6, 365-373, 2002
Disentangling the mystery of green bands of yttrium monohydride with the help of Stark spectroscopy
YH molecules were produced by laser vaporizing yttrium in the presence of He doped with H-2 or NH3. Stark spectra were recorded for four bands in the 19300-19800 cm(-1) region at electrostatic fields up to 16 kV/cm. Stark measurements proved useful in establishing rotational and Omega quantum number assignments. The permanent electric dipole moments (in Debye) were measured to be: 1.569(64), 2.325(8), 3.316(11), 2.273(6), and 1.537(8) for the X'Sigma(+) ground state and the 19385, 19746, 19572, and 19575 cm(-1) excited states, respectively. Strong variation of the effective Omega quantum number with J was detected for the 19572 cm(-1) state. (C) 2002 Elsevier Science B.V. All rights reserved.