Chemical Physics Letters, Vol.377, No.1-2, 74-80, 2003
Electron attachment to the DNA bases thymine and cytosine
Electron attachment (EA) to the DNA bases thymine (T) and cytosine (C) was studied in the electron energy range from about 0 to 9 eV using a crossed electron/molecule beams technique. As uracil the dominant negative ions formed via EA reactions to T and C are (T - H)(-) (corresponding to T minus H, with a mass to charge ratio of 125) and (C - H)(-) (corresponding to C minus H with a mass to charge ratio of 110). The respective partial EA cross-sections for (T - H)(-) and (C -H)(-) could be determined yielding peak values of sigma (1.05 eV) = 1.2 x 10(19) m(2), sigma (1.54 eV) = 2.3 x 10(-10) m(2), respectively. (C) 2003 Elsevier B.V. All rights reserved.