Chemical Physics Letters, Vol.378, No.1-2, 18-23, 2003
Electron transfer rate on mixed valence states of Class II/III transition for N,N'-diphenyl-1,4-phenylenediamine structures as a polyaniline unit
The first example of the determination of the electron transfer rate (lambda, V, DeltaG*, k(th)) for N,N'-diphenyl-1,4-phenylenediamine derivatives using the Marcus-Hush theory is described. These results were in good agreement with the ones obtained using variable-temperature IR spectra measurements. (C) 2003 Elsevier B.V. All rights reserved.