화학공학소재연구정보센터
Chemical Physics Letters, Vol.393, No.1-3, 192-196, 2004
On the partition function of Morse oscillators
Based on the cumulant approach, new analytical formulae are proposed to evaluate the vibrational partition function of Morse oscillators. These formulae give numerical values nearly identical to the exact values over the entire temperature range. The influence of rotation-vibration coupling is also taken into account. (C) 2004 Elsevier B.V. All rights reserved.