Chemical Physics Letters, Vol.397, No.4-6, 516-519, 2004
Growth mechanisms of carbon nanotubes converted from diamond-like carbon films
Trying to understand the growth mechanism of the carbon nanotubes (CNTs), a very simple growth approach was undertaken. Nanotubular structures were grown from diamond-like carbon (DLC) films. Vacuum annealing of DLC (C-sp(3) rich) films mixed with catalysts in argon atmosphere at 1000 degreesC leads to the formation of the nanotubular structures. In the same growth process graphite (100% C-sp(2)) does not promote to form CNTs. We proposed the growth mechanism in two step process: (1) conversion of C-sp(3) phase into C-sp(2) phase in the presence of the catalyst(s) at elevated temperature; (2) crystallization and rolling of c-sp(2) in tubular shape. (C) 2004 Elsevier B.V. All rights reserved.