Chemie Ingenieur Technik, Vol.69, No.4, 438-445, 1997
20 Years Development of a Bipolar Membrane Cell for Alkali Chloride Electrolysis from Laboratory to Global Application
First samples of perfluorinated cation exchange membranes were obtained in 1971. They were tested for use in the diaphragm process as a replacement for asbestos diaphragms. However, the special features of these membranes led to the decision to develop special new membrane electrolysis cells. A patent was sought for the first new cell design in 1975. After extensive material testing and many improvements, the HOECHST bipolar membrane cell was produced, consisting of an electrolyzer made up of individual elements, i.e. individual sealed electrolysis cells. Starting in 1982, this cell type was developed further in cooperation with UHDE GmbH. In 1983 it was installed for the first time in an industrial electrolysis plant. Despite strong competition, the bipolar HOECHST-UHDE membrane cell has now gained an important market share. In 1998 it will be installed worldwide in 43 electrolysis plants, with a total NaOH capacity then amounting to 2.5 million mtpa.