Kinetics of the CH3O2+NO2 reaction: A temperature and pressure dependence study using chemical ionisation mass spectrometry

Bacak A; Bardwell MW; Raventos-Duran MT; Percival CJ; Hamer PD; Shallcross DE

Chemical Physics Letters, Vol.419, No.1-3, 125-129, 2006

DOI10.1016/j.cplett.2005.11.070 Export Citation

Kinetics of the CH3O2+NO2 reaction: A temperature and pressure dependence study using chemical ionisation mass spectrometry

Bacak A, Bardwell MW, Raventos-Duran MT, Percival CJ, Hamer PD, Shallcross DE

The rate coefficient for the reaction CH3O2 + NO2 has been measured using a turbulent flow technique with high pressure chemical ionisation mass spectrometry for the detection of reactants. The rate constant was measured between 75 and 600 Torr and at 298 and 223 K. This work represents the first experimental evaluation of this rate coefficient at temperatures below 253 K. (c) 2005 Elsevier B.V. All rights reserved.