화학공학소재연구정보센터
Chemical Physics Letters, Vol.421, No.1-3, 47-51, 2006
Exact matrix computation of the statistical mechanics of a cell model of hard sphere phase behaviour
An exact calculation of the statistical mechanics of a cell model of hard-sphere isotherm behaviour is presented. Our calculation attributes the observed steps in the pressure-volume isotherms to entropic effects caused by the volume of space excluded by the hard core. (c) 2006 Elsevier B.V. All rights reserved.