Site-selective ion pair production via normal Auger decay of free CH3F molecules studied by electron-ion-ion coincidence spectroscopy

Fukuzawa H; Prumper G; Liu XJ; Kukk E; Sankari R; Hoshino M; Tanaka H; Tamenori Y; Ueda K

Chemical Physics Letters, Vol.436, No.1-3, 51-56, 2007

DOI10.1016/j.cplett.2007.01.030 Export Citation

Site-selective ion pair production via normal Auger decay of free CH3F molecules studied by electron-ion-ion coincidence spectroscopy

Fukuzawa H, Prumper G, Liu XJ, Kukk E, Sankari R, Hoshino M, Tanaka H, Tamenori Y, Ueda K

Site-specific fragmentation caused by C KVV and F KVV Auger decay of free CH3F molecules has been studied. Energy-resolved Auger electrons and pairs of mass-resolved ions were detected in coincidence. Strong enhancements for the production of CH3+-F+ and H+-CF+ ion pairs were found for the F KVV and C KVV Auger decays, respectively. (c) 2007 Elsevier B.V. All rights reserved.