Chemistry Letters, Vol.29, No.3, 224-225, 2000
Electron transfer process of ionically dimeric cobalt porphyrin accompanied with dissociation equilibrium
The ionically dimeric cobalt porphyrin with a II-II valence state undergoes a stepwise two-electron transfer accompanied with dissociation equilibrium (Kd = 1.3 x 10(-6) M) with redox potentials at -0.37 and -0.17 V vs. Fc/Fc(+).