Bis(mu-oxo)(mu-hydroxo)triiron(III) and (mu-oxo)(mu-hydroxo)diiron(III) core complexes with tripodal ligands having a terminal carboxylate

Furutachi H; Ohyama Y; Tsuchiya Y; Hashimoto K; Fujinami S; Uehara A; Suzuki M; Maeda Y

Chemistry Letters, Vol.29, No.10, 1132-1133, 2000

Furutachi H, Ohyama Y, Tsuchiya Y, Hashimoto K, Fujinami S, Uehara A, Suzuki M, Maeda Y

The tripodal ligands (6Me(2)-BPG and BPG) containing the carboxylate donor afford two types of Fe-2(O)(OH) and Fe-3(O)(2)(OH) core complexes, depending upon the methyl-substituent effect on the 6-position of the pyridyl ring.