Chemistry Letters, Vol.29, No.10, 1138-1139, 2000
A mixed-valence Mn(II,III) complex with a 2D structure: Crystal structure and magnetic property of K[Mn-2(mu-CrO4)(2)(mu-OH)(2)]
Reaction of MnSO4. 4H(2)O with K2CrO4 in water yielded highly crystalline black solids, which was chracterized to a 2D mixed valent Mn(II,III) complex, potassium di-mu -chromato-di-mu -hydroxo-dimanganate (1-) K[Mn-2(mu -CrO4)(2)(mu -OH)(2)] (1).