Chemistry Letters, Vol.32, No.1, 106-107, 2003
Unique three-dimensionally expanded nanoporous structure constructed with a Cu(I) and cis,cis-1,3,5-triaminocyclohexane having a 3-fold axial symmetry
Unique supramolecular crystal with a large macrocyclic channel structure has been prepared from the reaction of a [Cu-1(MeCN)(4)]SbF6 and cis, cis-1,3,5-triaminocyclohexane with a three-fold axial symmetry, whose channel is constructed from a distorted pseudofive-fold axial symmetric ring with a pore size of 5 x 12 (A) over circle (2).