C-H activation by Cu(III)(2)O-2 intermediate with secondary amino ligand

Arii H; Saito Y; Nagatomo S; Kitagawa T; Funahashi Y; Jitsukawa K; Masuda H

Chemistry Letters, Vol.32, No.2, 156-157, 2003

DOI10.1246/cl.2003.156 Export Citation

C-H activation by Cu(III)(2)O-2 intermediate with secondary amino ligand

Arii H, Saito Y, Nagatomo S, Kitagawa T, Funahashi Y, Jitsukawa K, Masuda H

Reaction of Cu(I) complex having a newly designed tridentate ligand i-Bu3CY with dioxygen has given an active bis(mu-oxo)dicopper(III) complex, which has exhibited a unique intramolecular hydroxylation of the beta-methine carbon of isobutyl group of the ligand.