화학공학소재연구정보센터
Chemistry Letters, Vol.34, No.8, 1182-1183, 2005
Estimation of thermodynamic parameters on enantioselective complexation equilibria by temperature-dependent FAB mass spectrometry
The relative thermodynamic parameters, Delta Delta G degrees (enan(R/S)), Delta Delta H degrees (enan(R/S)), and Delta Delta S degrees (enan(R/S)), on the enantioselective host-guest complexation equilibria were estimated easily using the temperature-dependent FAB mass spectrometry coupled with the enantiomer labeled guest method.