화학공학소재연구정보센터
Chemistry Letters, Vol.35, No.5, 498-499, 2006
The employment of indium nanoparticles in Barbier-type reaction of allylic chloride in water
Indium nanoparticles have been employed in the reactions of various carbonyl compounds with allyl (crotyl) chloride in water, affording the corresponding alcohols with high yields. The crotylation gave exclusive gamma-adducts with a dominant syn-isomer.