Chemistry Letters, Vol.35, No.9, 1042-1043, 2006
Occurrence of the spin-crossover phenomenon of assembled complexes, Fe(NCX)(2)(bpa)(2) (X = S, BH3; bpa=1,2-bis(4-pyridyl)ethane) by enclathrating organic guest molecule
Two assembled complexes, Fe(NCX)(2)(bpa)(2) (X = S, BH3; bpa = 1,2-bis(4-pyridyl)ethane), enclathrating biphenyl or 1,4-dichlorobenzene have been synthesized, whose skeletons are 1D chain, and are revealed to show spin-crossover phenomenon. Transition temperature changes depending on anion and guest molecules.