The experimental results of the process of epoxidation of allylic compounds (allyl alcohol, methallyl alcohol and methallyl chloride) to corresponding epoxides with hydrogen peroxide over titanium silicalite: TS-1, TS-2, Ti-beta and Ti-MCM-41 have been presented. The epoxidation was carried out with a 30% hydrogen peroxide in methanol as solvent in an autoclave. ne applied epoxidation system allowed to obtain glycidol, P-methylglycidol and beta-methylepichlorohydrin with a good selectivity and conversion of allylic compounds in most cases. The major applications of glycidol, P-methylglycidol and beta-methylepichlorohydrin have been also presented. (C) 2004 Elsevier B.V. All rights reserved.