In the presence of hydrogen and of (R,R)-ethylenebis tetrahydroindenyl zirconium dichloride activated by methylalumoxane, the styrene can be fully converted into low molecular weight compounds. The kinetic picture of the hydrooligomers formation is made complicated by the irregular regiochemistry of the styrene insertion. However the study on the effect of the feed composition on the products composition allows inferring mechanistic hypothesis and optimizing the formation of the chiral product, (R)-1,3-diphenylbutane. The subsequent functionalization of this molecule, without loss of chirality, discloses the potentiality of such kind of catalytic system for the synthesis of optically active synthones. (c) 2005 Elsevier B.V. All rights reserved.