The synthesis of NaA zeolite membrane on a porous alpha -Al2O3 support by microwave heating (MH) was investigated. The formation of a NaA zeolite membrane was drastically promoted by MH. The synthesis time was reduced from 3 h for conventional heating (CH) to 15 min for MH. Surface seeding cannot only promote the formation of NaA zeolite on the support, but also inhibit the transformation of NaA zeolite into other types of zeolites. The thickness of the NaA zeolite membrane synthesized by MH was about 4 mum, thinner than that of NaA zeolite membrane synthesized by CH. The permeance of NaA zeolite membrane synthesized by MH was four times higher than that of the NaA zeolite membrane synthesized by CH, while their permselectivities were comparable. Multi-stage synthesis resulted in the transformation of NaA zeolite into other types of zeolites, and the perfection of the as-synthesized membrane decreased. The formation mechanism of NaA zeolite membrane on the porous alpha -Al2O3 support by MH was proposed. The promotion effect on the formation of NaA zeolite membrane by MH can be divided into two parts: the "thermal effect" and the "microwave effect". The formation of a homogeneous and thin NaA zeolite membrane resulted from both the "thermal effect" and the "microwave effect", while the fast formation of NaA zeolite membrane was mainly caused by the "microwave effect".