Journal of Hazardous Materials, Vol.107, No.3, 115-121, 2004
Integrated Fenton's reagent-coagulation/flocculation process forthe treatment of cork processing wastewaters
In the present work two methods were tested for the treatment of cork processing wastewaters. In a first phase, a coagulation/flocculation method was applied using FeCl3 as flocculating agent and Ca(OH)(2) as base-precipitant. One cycle of the treatment (1000 ppm of FeCl3) reduced chemical oxygen demand (COD), total polyphenols and aromatic compounds of the effluent by 45, 71 and 58%, respectively. Two cycles of treatment (2 x 1000 ppm of FeCl3) increase these reductions until values of 67, 92 and 85%, respectively. In a second phase, an integrated Fenton-coagulation/flocculation process was applied (this second method only requires the addition of H2O2). One cycle of the integrated process (1000 ppm of FeCl3 and 0.5 mol/l of H2O2) reduced the COD, total polyphenols and aromatic compounds of the effluent by 74, 99 and 98%, respectively, which supposes, a considerable improvement compared with the first method. (C) 2003 Elsevier B.V. All rights reserved.