Synthesis, characterization and thermolysis studies on triazole and tetrazole based high nitrogen content high energy materials

Sivabalan R; Anniyappan M; Pawar SJ; Talawar MB; Gore GM; Venugopalan S; Gandhe BR

Journal of Hazardous Materials, Vol.137, No.2, 672-680, 2006

DOI10.1016/j.jhazmat.2006.03.038 Export Citation

Synthesis, characterization and thermolysis studies on triazole and tetrazole based high nitrogen content high energy materials

Sivabalan R, Anniyappan M, Pawar SJ, Talawar MB, Gore GM, Venugopalan S, Gandhe BR

This paper reports the synthesis, characterisation and thermolysis studies of hydrazinium azotetrazolate (HAZ) and 1,1'-dinitro-3,3'-azo-1,2,4-triazole (N-DNAT). TGA and DSC results suggested that HAZ decomposes in the range of 150-180 degrees C and N-DNAT in the range of 160-170 degrees C, respectively. The pattern of decomposition of HAZ dihydrate and N-DNAT has been predicted with the help of pyrolysis GUMS technique and a probable decomposition mechanism has been proposed. The theoretically predicted performance data suggests the potential nature of HAZ and N-DNAT for their use in propellant/explosive as well as in gas generator formulations. (c) 2006 Elsevier B.V. All rights reserved.

Keywords:high nitrogen content high energy materials (HNC-HEMs);hydrazinium azotetrazolate;dinitroazotriazole;synthesis;thermolysis