The electrical performance of multilayer ceramic capacitors (MLCCs) with Ni inner electrodes, made from (Ba,Ca)-(Ti,Zr,Mn)O-3 (BCTZM), is closely related to the calcination temperature and the A/B ratio of the powder. For materials showing A/B = 1.000, the lifetime, the breakdown voltage, and the RC increase with higher calcination temperatures. No significant effect of the calcination temperature on RC and lifetime was found for materials showing A/B = 0.991, The isoelectric point of BCTZM is shifted toward higher pH values when the calcination temperature is decreased. The above results are attributed to the colloidal stability of aqueous BCTZM suspensions and the resulting green density of powder compacts.