Effects of matrix cracks and the attendant interface debonding and sliding on both the longitudinal and the transverse thermal diffusivities of a unidirectional Nicalon/MAS composite are investigated. The diffusivity measurements are made in situ during tensile testing using a phase-sensitive photothermal technique. The contribution to the longitudinal thermal resistance from each of the cracks is determined from the longitudinal diffusivity along with measurements of crack density. By combining the transverse measurements with the predictions of an effective medium model, the thermal conductance of the interface (characterized by a Biot number) is determined and found to decrease with increasing crack opening displacement, from an initial value of approximate to 1 to approximate to 0.3. This degradation is attributed to the deleterious effects of interface sliding on the thermal conductance. Corroborating evidence of degradation in the interface conductance is obtained from the inferred crack conductances coupled with a unit cell model for a fiber composite containing a periodic array of matrix cracks. Additional notable features of the material behavior include: (i) reductions of approximate to 20% in both the longitudinal and the transverse diffusivities at stresses near the ultimate strength, (ii) almost complete recovery of the longitudinal diffusivity following unloading, and (iii) essentially no change in the transverse diffusivity following unloading. The recovery of the longitudinal diffusivity is attributed to closure of the matrix cracks. By contrast, the degradation in the interface conductance is permanent, as manifest in the lack of recovery of the transverse diffusivity.