화학공학소재연구정보센터
Journal of the American Ceramic Society, Vol.84, No.10, 2165-2169, 2001
In situ densification behavior in the pyrolysis consolidation of amorphous Si-N-C bulk ceramics from polymer precursors
In situ consolidation of amorphous Si-N-C ceramics during pyrolysis of polymer precursor provides a way to consolidate bulk silicon nitride based ceramics at lower temperatures. Porosity evolution during polymer-ceramic conversion has been investigated to clarify the densification process. A densification mechanism based on surface reaction and pyrolysis accommodated by viscous flow has been proposed.