화학공학소재연구정보센터
Journal of the American Ceramic Society, Vol.85, No.4, 989-991, 2002
Oxidation behavior from room temperature to 1500 degrees C of 3D-C/SiC composites with different coatings
A carbon-fiber-reinforced silicon carbide composite (3D-C/SiC) was prepared by chemical vapor infiltration. A SiC and SiC/Si-Zr coating were deposited on the composite to investigate the effect of different coatings on the oxidation behavior of 3D-C/SiC composites. The 3D-C/SiC(SiC/Si-Zr) composite decreased in weight below 1000degreesC and increased in weight above 1000degreesC. With an increasing oxidation time, the weight loss increased greatly and the weight gain increased little. The 3D-C/SiC(SiC) composite always decreased in weight over the full temperature range. With an increasing oxidation time, the weight loss increased rapidly below 1000degreesC and reached its minimum value at 1400degreesC. The 3D-C/SiC(SiC/Si-Zr) composite had a higher oxidation resistance above 1000degreesC, and the 3D-C/SiC(SiC) composite had a higher oxidation resistance below 1000degreesC. The wider the coating cracks, the larger the maximum weight loss and the lower the temperature corresponding to the maximum weight loss. With an increasing oxidation time, the activation energy of the 3D-C/SiC(SiC/Si-Zr) composite increased from 96 to 138 kJ/mol, and the 3D-C/SiC(SiC) composite increased from 130 to 180 kJ/mol.