화학공학소재연구정보센터
Journal of the American Ceramic Society, Vol.85, No.6, 1512-1516, 2002
Microstructure and mechanical properties of silicon nitride ceramics with controlled porosity
Porous silicon nitride ceramic with a porosity from 0-0.3 was fabricated by partial hot-pressing of a powder mixture of alpha-Si3N4 and wt% Yb2O3 as sintering additive. Irrespective of the porosity, the samples exhibited almost the same microstructural features including grain size, grain aspect ratio, and pore size. Porosity dependences of Young's modulus, flexural strength, and fracture toughness (K-IC) were investigated. All these properties decreased with increasing porosity. However, because of the fibrous microstructure. the decreases of flexural strength and fracture toughness were moderate compared with the much greater decrease of Young's modulus. Thus, the strain tolerance (fracture strength/Young's modulus) increased with increasing porosity. The critical energy release rate also increased slightly with an increasing volume fraction of porosity to 0.166 and remained at the same level with that of the dense sample when the porosity was 0.233. They decreased as porosity increased further.