The densification of aluminum nitride using Ca12Al14O33 as a sintering aid has been studied with emphasis on the effect of using coarse or fine powder, the amount of sintering aid, the sintering temperature, and embedding. Both crystalline and amorphous grain boundary phases were observed. Significant weight losses were observed for coarse-grained samples, and if suitable embedding was not used. Porous and coarse-grained ceramics with high contiguity and minor amounts of secondary phases were obtained by enhanced evaporation while dense ceramics were obtained limiting the evaporation. High weight losses in the graphite environment resulted in formation of a dense AlN surface layer.