화학공학소재연구정보센터
Journal of the American Ceramic Society, Vol.86, No.10, 1645-1650, 2003
A simple direct casting route to ceramic foams
A simple direct foaming and casting process using ovalbumin-based aqueous slurries for fabricating ceramic and metal foams is demonstrated. Foaming of aqueous ceramic slurries and the foam microstructure were seen to be a strong function of slurry rheology. Setting of foams with ceramic solids loading above 20 vol% was achieved by addition of acid, which also prevented binder migration. Acid addition resulted in excessive shrinkage, causing cracking of foams with ceramic loading below 20 vol%. Addition of sucrose to the slurries suppressed shrinkage leading to defect-free foams with porosity exceeding 95%. Overall porosity and foam microstructure could be controlled through ceramic solids loading, ovalbumin-water ratio, foaming time and sucrose amount, and sintering temperature. The ceramic foams fabricated by the process were strong enough to be green machined to different shapes.