Journal of the American Ceramic Society, Vol.88, No.4, 845-849, 2005
High-temperature oxidation at 1500 degrees and 1600 degrees C of SiC/graphite coated with sol-gel-derived HfO2
Oxidation of SiC compositionally graded (SCGed) graphite coated with HfO2 derived from HfCl4 by a sol-gel process was performed at 1500 degrees and 1600 degrees C in a flowing gas mixture of Ar and O-2 (80/20 kPa). SCGed graphite was produced by reaction of graphite with either molten Si or SiO gas at 1450 degrees C. The sol-gel-derived HfO2 precursor was deposited on SCGed graphite by a dip-coating method. Isothermal and cyclic oxidation of uncoated- and HfO2-coated SCGed graphite was studied by monitoring overall weight change using an electro-microbalance. Scanning electron microscopy with energy-dispersive Xray analysis was used to observe the surfaces and cross-sections of the oxidized HfO2-coated SCGed graphite. The formation of HfSiO4 was confirmed on the outer layer of the oxidized sample, beneath which a thin silica layer was formed. The improved oxidation resistance of SCGed graphite by coating with HfO2 is discussed on the basis of the formation of these two layers.