Journal of the American Ceramic Society, Vol.89, No.1, 189-192, 2006
Improved aging characteristics of NTC thermistor thin films fabricated by a hybrid sol-gel-MOD process
Negative temperature coefficient thermistor oxide thin films with improved aging characteristics are described. Better thermal stability has been achieved by incorporating sol-gel techniques with metallo-organic decomposition methods. A compositional range was identified whereby borosilicate may incorporate into the thermistor oxides, forming nanocomposites showing thermistor electrical characteristics. Thermistor thin films, with composition Ni(0.48)Co(0.24)Cu(0.6)Mn(1.68)O(4)center dot 0.22SiO(2)center dot 0.15B(2)O(3) were deposited onto glass substrates from a solution containing organic transition metal salts, tetraethyl orthosilicate and triethyl borate. Electrical resistance measurements verified characteristic thermistor behavior. Nanocomposite thin films exhibited a factor of four improvement as compared with pure oxides after aging at 150 degrees C for 500 h.