Journal of the American Ceramic Society, Vol.89, No.2, 740-742, 2006
Formation of silicon-doped boron nitride bamboo structures via pyrolysis of a polymeric precursor
In this paper, we report the growth of bamboo-like silicon-doped boron nitride nanotubes via catalyst-assisted pyrolysis of a boron-containing polymeric precursor. The morphologies and structures of the nanotubes were characterized using electron microscopy and Raman spectroscopy. Two types of nanotubes are observed, one from a base-growth mode and the other from a tip-growth mode. The type II nanotubes contain encapsulated catalytic nanoparticles at the tip of every compartment. This unique structure is a promising candidate for applications in many nanodevices.