The room-temperature freeze-casting method was used to fabricate porous bioactive glass-ceramics. In this method, a glass/camphene slurry prepared at 60 degrees C was cast into a mold at 20 degrees C, resulting in the production of a rigid green body that was comprised of three-dimensional dendritic camphene networks surrounded by highly concentrated glass powder walls. After the sublimation of camphene, the samples were sintered for 3 h at elevated temperatures ranging from 700 degrees to 1100 degrees C. As the sintering temperature was increased to 1000 degrees C, the densification of the glass-ceramic wall was remarkably enhanced, while its highly porous structure was preserved. The sample sintered at 1000 degrees C showed a high porosity of 53% and pore channels with a size of several tens of micrometers, as well as dense glass-ceramic walls. In addition, the fabricated samples effectively induced the deposition of apatite on their surfaces when immersed in simulated body fluid, implying that they are very bioactive.