화학공학소재연구정보센터
Journal of the American Ceramic Society, Vol.89, No.11, 3560-3563, 2006
Characterization of chemical vapor-deposited (CVD) mullite plus CVD alumina plus plasma-sprayed tantalum oxide coatings on silicon nitride vanes after an industrial gas turbine engine field test
Silicon nitride ceramic vanes coated with chemical vapor-deposited (CVD) mullite, CVD alumina, and plasma-sprayed tantalum oxide were exposed to field tests in an industrial gas turbine engine. Results varied due to expected non-uniformities in the CVD coating microstructures, but dense CVD mullite/alumina showed excellent stability and protective capacity after 1148 h of engine testing. Surfaces without CVD coatings experienced massive intragranular subsurface oxidation and/or rapid recession of the ceramic substrate due to volatilization of silica species formed by oxidation. These results suggest that thin (< 5 mu m), dense, high-purity CVD mullite and CVD alumina are viable components for an environmental barrier coating system to protect structural ceramics in combustion environments.