Polycrystalline thin films of lithium cobalt oxide were grown by pulsed-laser deposition (PLD) technique. Films of LiCoO2 were deposited onto Si substrates heated at temperature lower than 300 degreesC from a sintered composite target (LiCoO2 + Li2O) irradiated with a Nd:YAG laser. The structural characterizations of these films were carried out by X-ray diffraction and Raman scattering spectroscopy, which probe the local environment of cations in the LiCoO2 framework. Raman spectra of PLD LiCoO2 films were investigated as a function of various growth conditions as substrate temperature, partial oxygen pressure in the deposition chamber, and target composition. PLD LiCoO2 films obtained with a polycrystalline morphology were successfully used as cathode materials in lithium microbatteries. The Li//LiCoO2 cells were tested by cyclic voltammetry and galvanostatic charge-discharge techniques in the potential range 2.0-4.2 V. Specific capacity as high as 195 mC cm(-2) mum was measured on polycrystalline films.