Corrosion of quasicrystalline and related crystalline phases coexisting in Al-Cu-Fe alloys with the compositions of Al60Cu27.5Fe12.5, Al62.5Cu25Fe12.5, Al65Cu20Fe15 and Al67.5Cu20Fe12.5 was studied in saline, acidic, neutral and basic solutions. The corrosion behaviour of the alloys was explored by potentiodynamic polarisation experiments, while the microstructural studies by X-ray diffraction and scanning electron microscopy yielded information on the phase structure and its changes as a result of the polarisation experiments. The results of the study indicated that the composition and relative amount of phases present in Al-Cu-Fe alloys are the key parameters defining the corrosion behaviour of the alloy. In saline solutions, the corrosion potentials were in the range where a homogeneous dissolution of the alloy, followed by a redeposition of Cu, took place, the corrosion rate being mainly determined by the amount of Cu-rich phases present in the structure. In acidic solutions, the Cu-rich phases remained untouched by corrosion, whereas phases containing less Cu were susceptible to corrosion. In neutral and basic solutions, oxidation was the primary surface reaction. However, Cu was found to introduce pores into the oxide layer and Fe to inhibit the oxidation process. Therefore, in neutral and basic solutions, the quasicrystalline phase, with intermittent Cu and Fe contents with respect to other phases present in the AI-Cu-Fe alloys studied, showed the best corrosion performance. (C) 2004 Elsevier B.V. All rights reserved.