Journal of Crystal Growth, Vol.219, No.1-2, 32-39, 2000
Growth of Pb1-xSnxTe (x approximate to 0.12) epitaxial layers by temperature difference under controlled vapor pressure liquid-phase epitaxy
Pb1-xSnxTe (x approximate to 0.12) liquid-phase epitaxial layers have been grown by the temperature difference method under controlled vapor pressure (TDM-CVP) using Pb solvents on PbTe substrates at temperatures 490 degrees C and 600 degrees C. The grown layers are usually n-type, and the optimum Te vapor pressure where the carrier concentration becomes minimum is 3.1 x 10(-3) > P-Te > 1.4 x 10(-3) Torr for T-g = 600 degrees C, and 3.1 x 10(-5) > P-Te > 1.4 x 10(-5) Torr for T-g = 490 degrees C. The activation energy of the optimum Te vapor pressure for Pb1-xSnxTe (x approximate to 0.12) is 2.38 eV, which is larger than the activation energy for PbTe, 2.12 eV. Two different types of etch pits are observed on Pb1-xSnxTe (x approximate to 0.12) layers. The density of the smaller size etch pits tends to become minimum at the optimum Te vapor pressure, while the larger size etch pits are dominantly observed at the vapor pressure region above the optimum vapor pressure. This tendency and lower electron mobility suggest defect aggregation taking place above the optimum vapor pressure.
Keywords:PbTe;Pb1-xSnxTe;liquid-phase epitaxy;TDM-CVP liquid-phase epitaxy;controlled vapor pressure